Synthesis, structure, and characterization of Cu4S10(4-methylpyridine)4
β Scribed by Aloysius F. Hepp; Robert M. Richman; Stan A. Duraj; Maria T. Andras; Hall L. Moore; Michal Sabat; William E. Eckles; Robert A. Martuch
- Book ID
- 105102551
- Publisher
- Springer
- Year
- 1996
- Tongue
- English
- Weight
- 631 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1040-7278
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π SIMILAR VOLUMES
## Abstract The tetranuclear Cu4OBrnCl(6-n)L4 complexes, where L = 3-methylpyridine (3-Mepy), 4-methylpyridine (4-Mepy) and n=0β6 with trigonal bipyramidal coordination of copper(II) were prepared and their infrared and electronic absorption spectra as well as cyclic voltammograms in nitromethane s
## Abstract Gaussian analysis of bands between 500 cmβ1 and 600 cmβ1 attributed to the $$ \tilde \nu $$ as (Cu4O) stretching vibration of the tetrahedral Cu4O core in Cu4OBrnCl(6βn)(4-Mepy)4 (n = 0β6) complexes showed two bands, symmetry reduction of the T 2 mode of vibration towards the A 1 and E
## Abstract Correlations involving bond lengths and bond angles in the molecular structure of the Cu4OCl6(4-Mepy)4 complex (4-Mepy = 4-methylpyridine) with four symmetrically independent molecules present in the unit cell showed that the donor-acceptor behavior involving the Ο-back donation into th