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Synthesis, structure, and bonding of the tetrameric cyclopentadienyliron sulfide monocation, [Fe4(.eta.5-C5H5)4(.mu.3-S)4]+: stereochemical consequences due to oxidation of a cubane-like iron sulfide (Fe4S4) core

โœ Scribed by Trinh Toan, ; Fehlhammer, W. Peter; Dahl, Lawrence F.

Book ID
127199322
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
795 KB
Volume
99
Category
Article
ISSN
0002-7863

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Photochemical formation and stereochemical characterization of two electronically equivalent but structurally different series of triangular dicobalt-metal clusters, MCo2(.eta.5-C5Me5)2(.mu.-CO)3(.mu.3-CO) [M = Cr(.eta.6-C6H5Me), Mn(.eta.5-C5H4Me), Fe(.eta.4-C4H4)] and MCo2(.eta.5-C5Me5)2(.mu.-CO)2(.mu.3-CO) [M = Fe(CO)3, Co(.eta.5(C5H4Me)]: a rational synthesis of mixed-metal clusters by photogenerated metal-fragment addition across a metal-metal multiple-bonded dimer
โœ Cirjak, Larry M.; Huang, Jin-Shun; Zhu, Zhong-He; Dahl, Lawrence F. ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 652 KB