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Synthesis, structure and bonding of 2-aminopyridinium heptamolybdate trihydrate

✍ Scribed by Pascual Román; Juan M. Gutiérrez-Zorrilla; Martín Martínez-Ripoll; Severino García-Blanco

Publisher
Springer
Year
1986
Tongue
English
Weight
723 KB
Volume
11
Category
Article
ISSN
0340-4285

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## Abstract Treatment of MoO~3~ with butan‐1‐amine (BuNH~2~) or pyrrolidine (PyrNH~2~) results in the formation of (BuNH~3~)~8~[(Mo~7~O~24~)(MoO~4~)]·3H~2~O (1; BuNH~3~ = butan‐1‐aminium) or (PyrNH~2~)~6~[(Mo~7~O~24~]·2H~2~O (2; PyrNH~2~ = pyrrolidinium), respectively. On irradiation with sunlight,