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Synthesis, structure and biological activity of nickel(II) complexes of 5-methyl 2-furfural thiosemicarbazone

✍ Scribed by El Mostapha Jouad; Gérald Larcher; Magali Allain; Amédée Riou; Gilles M Bouet; Mustayeen A Khan; Xuan Do Thanh


Book ID
108403636
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
429 KB
Volume
86
Category
Article
ISSN
0162-0134

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Methyl(2-phosphanylphenolato[P,O])nickel
✍ Joachim Heinicke; Mengzhen He; Attila Dal; Hans-Friedrich Klein; Olaf Hetche; Wi 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 404 KB 👁 2 views

Reactions of various substituted 2-phosphanylphenols 1a-f with half-molar amounts of cis-[MeNi(µ-OMe)(PMe 3 )] 2 have been found to yield square-planar methyl(2-phosphanylphenolato)(trimethylphosphane)nickel(II) complexes 2a-f. 2 J PP coupling constants of 305-316 Hz at low temperature indicate a tr