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Synthesis, structure, and biological activity of derivatives of [2,2]-para-cyclophane. 2. 4-Hydroxymethyl(acyloxymethyl, alkenyl)-[2,3]-para-cyclophanes

โœ Scribed by Zh. A. Mamyrbekova; Iv. A. Bekro; S. A. Soldatova; E. A. Ageev; V. N. Guryshev; A. T. Soldatenkov


Book ID
112713448
Publisher
Springer
Year
1994
Tongue
English
Weight
442 KB
Volume
28
Category
Article
ISSN
0091-150X

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Multibridged [3n]Cyclophanes, 1. Synthes
โœ Shinmyozu, Teruo ;Kusumoto, Shirou ;Nomura, Sachiyo ;Kawase, Haruo ;Inazu, Takah ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 453 KB ๐Ÿ‘ 2 views

The acid-catalyzed cyclization of a pseudogeminally substituted acetyl group and a chloromethyl group of tri-bridged cyclophane 7 , followed by reduction of the carbonyl group afforded (3,](1,2,3,5)cyclophane 3. One-step TosMIC coupling reaction of tetrabromide 12 and subsequent reduction of the car