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Synthesis, structural investigation and thermal analyses of a novel coordination compound [Cd(DAT)6](HTNR)2·3.5H2O (DAT = 1,5-diaminotetrazole, H2TNR = styphnic acid)

✍ Scribed by Yan Cui; Tong-Lai Zhang; Jian-Guo Zhang; Li Yang; Xiao-Chun Hu; Jin Zhang


Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
577 KB
Volume
889
Category
Article
ISSN
0022-2860

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A novel three-dimensional hybrid solid, [{(Cu 4 I 4 ) 2 H 2 O}{Cu 6 (mtz) 6 }] n (1) (Hmtz = 3,5-dimethyl-1,2,4-triazole), was synthesized under solvothermal condition. The structure of 1 consists of four-connected Cu 4 I 4 clusters and hexanuclear Cu 6 (mtz) 6 rings as secondary building units (SBU