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Synthesis, Structural Characterization, and Reactivity of Organolanthanides Derived from a New Chiral Ligand, ( R )-Bis(pyrrol-2-ylmethyleneamino)-1,1‘-binaphthyl

✍ Scribed by Xiang, Li; Wang, Qiuwen; Song, Haibin; Zi, Guofu

Book ID: 126093532
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 170 KB
Volume: 26
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om7006826

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## Abstract Reaction of (__R__)‐bis(pyrrol‐2‐ylmethyleneamino)‐1,1′‐binaphthyl (1H~2~) or (__R__)‐__N__,__N′__‐bis(pyridin‐2‐ylmethyl)‐1,1′‐binaphthyl‐2,2′‐diamine (2H~2~) with Zr(NMe~2~)~4~ (1 equiv.) gives chiral zirconium amides 1‐Zr(NMe~2~)~2~·C~7~H~8~ (4·C~7~H~8~) or 2‐Zr(NMe~2~)~2~ (6) in goo