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Synthesis, Structural Characterization, and Reactivity of Group 4 Metallacarboranes Containing the Ligand [Me 2 C(C 5 H 4 )(C 2 B 9 H 10 )] 3−

✍ Scribed by Wang, Yaorong; Liu, Dongmei; Chan, Hoi-Shan; Xie, Zuowei


Book ID
121360340
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
233 KB
Volume
27
Category
Article
ISSN
0276-7333

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Study of n-butane pyrolysis at high temperature in a flow system allows measurement of the sum of the rate constants of the initiation reactions (2) and of the Arrhenius parameters of the reactions Established data for kl/k2 allow estimation of kl for 951'K and this, with recent thermochemical da