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Synthesis, Structural Characterization, and Luminescence Studies of Gold(I) and Gold(III) Complexes with a Triphosphine Ligand

✍ Scribed by Bardají, Manuel; Laguna, Antonio; Orera, Víctor M.; Villacampa, M. Dolores


Book ID
127341598
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
105 KB
Volume
37
Category
Article
ISSN
0020-1669

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Synthesis of luminescent trinuclear gold
✍ Manuel Bardajı́; Antonio Laguna 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 149 KB

We have prepared a series of trinuclear gold(I) complexes containing bis(diphenylphosphinomethyl)phenylphosphine (dpmp) and several anionic S-donor ligands. The reaction of [(AuCl) 3 (m-dpmp)] with potassium ethyl xanthate afforded the trinuclear gold(I) complexes [Au 3 Cl 3 -x (S 2 COEt) x (m-dpmp)