Synthesis, Structural Characterization, and Luminescence Properties of Branched Palladium(II) and Platinum(II) Acetylide Complexes
β Scribed by Yam, Vivian Wing-Wah; Tao, Chi-Hang; Zhang, Lingjun; Wong, Keith Man-Chung; Cheung, Kung-Kai
- Book ID
- 118201877
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 203 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0276-7333
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## Abstract An acetylideβbridged dinuclear platinum(II) terpyridyl complex, [Pt(4β__p__βtolylβterpy)βiβphenylβ=β(4β²β__pβtolyl__βterpy)Pt](C10~4~)~2~ (1). has been successfully synthesized and its photophysical properties are reported.
## Abstract Stepwise syntheses of monometallic palladium(II) and bimetallic palladium(II)/platinum(II) complexes were carried out in order to measure the metallophilicity of potential tetradentate bis(alkylthio)ylidenemalonato ligands. The reaction of [Pd](SO~4~) ([Pd] = (Me~4~en)Pd; Me~4~en = __N_