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Synthesis, structural characterization and cytotoxic activity of organotin derivatives of indomethacin

✍ Scribed by Carlos Camacho-Camacho; Irma Rojas-Oviedo; M. Angeles Paz-Sandoval; Jorge Cárdenas; Alfredo Toscano; Marcel Gielen; Lidia Barrón Sosa; Francisco Sánchez Bártez; Isabel Gracia-Mora

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
171 KB
Volume
22
Category
Article
ISSN
0268-2605

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The titanocene vinylidene intermediate [Cp\* 2 Ti=C=CH 2 ] (9) The azatitanacyclobutane [Cp\* 2 Ti{ϪNPhϪC(Ph)(H)Ϫ(C= CH 2 )Ϫ}] (22) was formed from the reaction between 9 and reacted with the carbodiimides RϪN=C=NϪR [R = p-CH 3 C 6 H 4 (19a), C 6 H 11 (19b)] to give the N=C-cycloaddition benzylidene