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Synthesis, Structural Characterization, and Computational Studies of Novel Diiodine Adducts with the Heterocyclic Thioamides N -Methylbenzothiazole-2-thione and Benzimidazole-2-thione: Implications with the Mechanism of Action of Antithyroid Drugs

✍ Scribed by Corban, Ghada J.; Hadjikakou, Sotiris K.; Hadjiliadis, Nick; Kubicki, Maciej; Tiekink, Edward R. T.; Butler, Ian S.; Drougas, Evangelos; Kosmas, Agnie M.


Book ID
120387466
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
198 KB
Volume
44
Category
Article
ISSN
0020-1669

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## Abstract The reaction of 2‐mercaptopyridine (C~5~H~5~NS or PYSH) with diiodine in a molar ratio of 1:2 in dichloromethane led to the oxidation and dimerization of the ligand and formation of [(PYS−PYSH)^+^·I~3~^−^]. The compound was characterised by elemental analysis, DTA‐TG, FT‐Raman, FT‐IR, U