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Synthesis, Structural Characterisation and Reactions of Some Vinylgold(I) Phosphane Complexes

✍ Scribed by Fabian Mohr; Larry R. Falvello; Mariano Laguna

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
118 KB
Volume
2006
Category
Article
ISSN
1434-1948

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Synthesis, Structural Characterisation and Electrochemical Studies of Neutral Alkenylcarbyne Tungsten Complexes Bearing Chelating Bidentate and Tridentate Phosphanes
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Neutral alkenylcarbyne complexes [X = SCN; n = 1 (2a), 4 (2b). X = OCN; n = 1 (2c), 4 (2d)] were prepared by reaction of the acetonitrile complexes [n = 1 (1a), 4 (1b)] with M[OCN] or M[SCN] (M = Na, K, Bu 4 N), and were fully characterised. The synthesis of complex 3, containing the tridentate phos