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Synthesis, structural analysis of the hetero-bimetallic complexes MMe[(O-2,4-tBu2C6H2-6-CH2)2(μ2-O-2,4-tBu2C6H2-6-CH2)N][Me2Al(μ2-OiPr)] [M = Zr, Hf] and their use in catalysis for ethylene polymerisation

✍ Scribed by Takii, Yuki; Inagaki, Akiko; Nomura, Kotohiro


Book ID
120614269
Publisher
Royal Society of Chemistry
Year
2013
Tongue
English
Weight
454 KB
Volume
42
Category
Article
ISSN
1477-9226

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Two nickel complexes [Ni(NH 2 CH 2 CH 2 CH 2 NH 2 ) 3 ]Cl 2 (1) and[Ni(C 6 H 4 N 2 H 4 ) 2 Cl 2 ] (2) have been obtained and characterized by IR and single crystal X-ray diffraction analysis. In complex 1, the nickel atom was in a chiral pseudo-octahedral [NiN 6 ] geometry environment, which was coo