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Synthesis, stereochemistry, and base-catalyzed rearrangement of 9-alkyl-2,4-dimethylthioxanthene-N-(p-toluenesulfonyl)sulfilimines

✍ Scribed by Tamura, Yasumitsu; Mukai, Chisato; Nakajima, Noriko; Ikeda, Masazumi


Book ID
126429778
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
693 KB
Volume
45
Category
Article
ISSN
0022-3263

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## Abstract Alkylation of 3‐oxo‐1,2‐thiazetidine 1,1‐dioxide 2 yields the __N__‐alkylated 3‐oxo‐β‐sultams 3a‐i. Solvolysis with NaOH or NH~3~ selectively opens the Nο£ΏS bond forming the sulfonate carboxamides 4 and the sulfonamidocarboxamides 7, respectively. Furthermore, the hitherto unknown compou