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Synthesis, stereochemistry and adsorption studies of new spiranes and polyspiranes containing 1,2-dithiolane units

✍ Scribed by Radu A. Gropeanu; Mihaela L. Ţînţaş; Catherine Pilon; Mario Morin; Livain Breau; Raluca Turdean; Ion Grosu


Book ID
102339218
Publisher
Journal of Heterocyclic Chemistry
Year
2007
Tongue
English
Weight
479 KB
Volume
44
Category
Article
ISSN
0022-152X

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✦ Synopsis


Abstract

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The synthesis and stereochemistry of a series of new cyclic disulfides containing (poly)spirane 1,2‐dithiolane units are reported. Also included is a study of the self‐assembled monolayers (SAMs) of these compounds on a gold surface. The characteristics of the resultant SAMs were determined by IR spectroscopy using molecular mechanics calculations.


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