Synthesis, stereochemistry and adsorption studies of new spiranes and polyspiranes containing 1,2-dithiolane units
✍ Scribed by Radu A. Gropeanu; Mihaela L. Ţînţaş; Catherine Pilon; Mario Morin; Livain Breau; Raluca Turdean; Ion Grosu
- Book ID
- 102339218
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2007
- Tongue
- English
- Weight
- 479 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0022-152X
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✦ Synopsis
Abstract
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The synthesis and stereochemistry of a series of new cyclic disulfides containing (poly)spirane 1,2‐dithiolane units are reported. Also included is a study of the self‐assembled monolayers (SAMs) of these compounds on a gold surface. The characteristics of the resultant SAMs were determined by IR spectroscopy using molecular mechanics calculations.
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