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Synthesis, Stabilities, and Redox Behavior of Di(1-azulenyl)(6-azulenyl)methylium Hexafluorophosphates. Generation of a Donor−Acceptor-Substituted Neutral Radical by Azulenes

✍ Scribed by Ito, Shunji; Kubo, Takahiro; Morita, Noboru; Ikoma, Tadaaki; Tero-Kubota, Shozo; Tajiri, Akio

Book ID
127347904
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
220 KB
Volume
68
Category
Article
ISSN
0022-3263

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1,2-Di(6-azulenyl)tetraphenylbenzenes and (6-azulenyl)pentaphenylbenzenes were synthesized by Diels-Alder reaction of di(6-azulenyl)acetylenes and 6-(phenylethynyl)azulenes with tetraphenylcyclopentadienone. Mono(6-azulenyl)benzenes exhibited a reduction wave upon cyclic voltammetry (CV). In contras

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