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Synthesis, spectroscopy, fluorescence and crystal structures of cyclopalladated dinuclear complexes with C, N-chelating azobenzenes and N, S-bridging heterocyclic-2-thiolates

✍ Scribed by Lobana, Tarlok S.; Sandhu, Amanpreet K.; Kaur, Amanpreet; Jasinski, Jerry P.

Book ID: 120552104
Publisher: Elsevier Science
Year: 2014
Tongue: English
Weight: 509 KB
Volume: 751
Category: Article
ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2013.07.003

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## Abstract The synthesis and crystal structures of three nonheme diiron(III) complexes with a tridentate N,N,O Schiff‐baseligand, 2‐({[2‐(dimethylamino)ethyl]imino}methyl)phenol (HL), are reported. Complexes [Fe~2~OL~2~(NCO)~2~] (1a) and [Fe~2~OL~2~(SAL)~2~]·H~2~O [SAL = __o__‐(CHO)C~6~H~4~O^–^] (