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Synthesis, spectroscopy and crystal structure determination of heteroleptic cobalt(II) silanethiolates with pyridine derivatives

✍ Scribed by Agnieszka Pladzyk; Katarzyna Baranowska; Patrycja Hapter

Publisher
Springer
Year
2010
Tongue
English
Weight
391 KB
Volume
35
Category
Article
ISSN
0340-4285

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## Abstract Two novel binuclear nickel(II) and cobalt(III) complexes with two or three dissimilar bridges, [Ni~2~(tacn)~2~(__ΞΌ__‐N~3~)~2~(__ΞΌ__‐O~2~CPh)](ClO~4~)β‹…H~2~O (1) and [Co~2~(tacn)~2~(__ΞΌ__‐N~3~)(__ΞΌ__‐OH)(__ΞΌ__‐O~2~CPh)](ClO~4~)~3~ (2) (tacn=1,4,7‐triazacyclononane), were synthesized and s