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Synthesis, spectroscopic and crystallographic characterization of the cobalt(III) ternary mixed-ligand complexes of N(4)-allyl/methyl thiosemicarbazones,N,N,N′,N′-tetramethylethylenediamine and azide

✍ Scribed by Tülay Bal-Demirci; Mehmet Akkurt; Şerife Pınar Yalçın; Orhan Büyükgüngör

Publisher: Springer
Year: 2009
Tongue: English
Weight: 359 KB
Volume: 35
Category: Article
ISSN: 0340-4285
DOI: 10.1007/s11243-009-9300-2

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## Abstract Two neutral complexes [(L~6~^3^4M)Fe~2~Cl~4~]·2H~2~O·2CHCl~3~ (1) and [(L~6~^3^4M)Mn~2~Cl~4~]·CH~3~CN (2) have been synthesized {L~6~^3^4M = __N__,__N__,__N′__,__N′__‐tetrakis[(6‐methyl‐2‐pyridyl)methyl]propane‐1,3‐diamine} and their molecular structures established by X‐ray crystallogr