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Synthesis, spectroscopic and a ZINDO study of cis- and trans-(X2)bis(4,4′-dicarboxylic acid-2,2′-bipyridine)ruthenium(II) complexes (X=Cl−, H2O, NCS−)

✍ Scribed by Md.K. Nazeeruddin; S.M. Zakeeruddin; R. Humphry-Baker; S.I. Gorelsky; A.B.P. Lever; M. Grätzel


Book ID
108314862
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
136 KB
Volume
208
Category
Article
ISSN
0010-8545

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✍ Roberto Gobetto; Giuseppe Caputo; Claudio Garino; Simona Ghiani; Carlo Nervi; Lu 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 245 KB

## Abstract A series of photoactive complexes of [Ru^II^bis(bipyridyl){2‐(4‐methylpyridin‐2‐yl)benzo[__d__]‐X‐azole}](PF~6~)~2~ (X = N–CH~3~, 1; S, 2; or O, 3) have been synthesized and fully characterized by proton and ^13^C NMR spectroscopy and UV/Vis spectroscopy. The X‐ray structure of 1 is als