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Synthesis, spectral properties, and reactions of manganese and rhenium pentacarbonyl phosphine and phosphite cation derivatives and related complexes

✍ Scribed by Drew, D.; Darensbourg, D. J.; Darensbourg, M. York.

Book ID
127127247
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
852 KB
Volume
14
Category
Article
ISSN
0020-1669

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## Abstract Mixed N‐heterocyclic carbene‐substituted phosphine and phosphite complexes of rhodium were prepared, starting from [Rh(COE)~2~Cl]~2~ (COE=cyclooctene) by addition of free N‐heterocyclic carbenes (NHC) and PR~3~. All new complexes were characterized by spectroscopy. In addition, the stru