Synthesis, Spectral Characterisation and Crystal Structure of (1,24-Bicyclophthalocyaninato)bismuth(III)

✍ Scribed by Karim Benihya; Mireille Mossoyan-Déneux; Michel Giorgi

• Publisher: John Wiley and Sons
• Year: 2001
• Tongue: English
• Weight: 425 KB
• Volume: 2001
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/1099-0682(200105)2001:5<1343::aid-ejic1343>3.0.co;2-e

✦ Synopsis

A new orange bicyclophthalocyanine complex of bismuth(III), [Bi(C 48 H 24 N 13 )], has been synthesised by means of the template reaction of bismuth(III) acetate with phthalodinitrile. The ligand consists of the phthalocyanine skeleton, which is bridged by two additional isoindole units. The conjugation of the phthalocyanine ring is interrupted by the two bridgehead sp 3 -hybridised carbon atoms. The main difference between this new bicyclophthalocyanine and those previously reported in the literature lies in the position of the bridgehead carbon atoms. In order to differentiate between these bicyclophthalocyaninato complexes, we propose a nomenclature: [Bi(C 48 H 24 N 13 )] is named Bi(1,24-Pcc), and the