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Synthesis, solid-state structure and reactivity of [PhTtPh]Cu

✍ Scribed by Carl Ohrenberg; Charles G Riordan; Louise Liable-Sands; Arnold L Rheingold

Publisher: Elsevier Science
Year: 1998
Tongue: English
Weight: 179 KB
Volume: 174
Category: Article
ISSN: 0010-8545
DOI: 10.1016/s0010-8545(98)00083-6

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✦ Synopsis

In acetonitrile solution, 1 is monomeric. X-ray analysis shows that 1 forms an infinite, one-dimensional solid-state extended structure. Each copper ion is coordinated by three sulfur donors, two from one ligand and the third from a second ligand. The approximate tetrahedral coordination sphere is completed by an

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