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Synthesis, reactivity and crystal structure of trimesitylgermylamine, Mes3GeNH2

✍ Scribed by Monique Rivière-Baudet; Alain Morère; James F. Britten; Mario Onyszchuk

Book ID
107812172
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
209 KB
Volume
423
Category
Article
ISSN
0022-328X

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A stable silagermene (tBu3Si)2Si=Ge(mes)
A stable silagermene (tBu3Si)2Si=Ge(mes)2 (mes = 2,4,6-trimethylphenyl): Synthesis, X-ray crystal structure, and thermal isomerization
✍ Masayasu Igarashi; Masaaki ıchinohe; Akira Sekiguchi 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 106 KB

## Abstract A stable silagermene, 1,1‐bis(tri‐tert‐butylsilyl)‐2,2‐bis(2,4,6‐trimethylphenyl)silagermene, was synthesized by the reaction of dilithiosilane (^t^Bu~3~Si)~2~SiLi~2~ with dichlorodimesitylgermane. Its structure was determined by spectroscopic data and X‐ray crystallography, which showe