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Synthesis, reactivity and catalytic properties of the allenylidene [Ru(CCCPh2)Cp(PTA)(PPh3)](CF3SO3) (PTA = 1,3,5-triaza-7-phosphaadamantane)

✍ Scribed by Serrano-Ruiz, Manuel; Lidrissi, Chaker; Mañas, Sonia; Peruzzini, Maurizio; Romerosa, Antonio


Book ID
121260834
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
763 KB
Volume
751
Category
Article
ISSN
0022-328X

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## Abstract Addition of BH~3~ to 1,3,5‐triaza‐7‐phosphaadamantane (PTA) leads to the formation of the first coordination complex of PTA in which a nitrogen and not the phosphorus of PTA is involved in the bonding. Multinuclear NMR spectroscopy, X‐ray crystallography, and computational chemistry are

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## Abstract A series of compounds of general formula [Ru(η^6^‐__p__‐cymene)(R~2~acac)(PTA)][X] (R~2~acac = Me~2~acac, __t__Bu~2~acac, Ph~2~acac, Me~2~acac‐Cl; PTA = 1,3,5‐triaza‐7‐phosphaadamantane; X = BPh~4~, BF~4~), and the precursor to the Me~2~acac‐Cl derivative [Ru(η^6^‐__p__‐cymene)(Me~2~aca