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Synthesis, reactions, and x-ray crystal structure determination of hafnocene complex Cp2Hf(isobutylene).cntdot.PMe3

โœ Scribed by Buchwald, Stephen L.; Kreutzer, Kristina A.; Fisher, Richard A.


Book ID
126867964
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
283 KB
Volume
112
Category
Article
ISSN
0002-7863

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Half-Sandwich Pentamethylcyclopentadieny
โœ Herberhold, Max ;Ji, Guo-Xin ;Rheingold, Arnold L. ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 407 KB

Half-sandwich complexes ,/ Iridium complexes ,/ cyclo-Sulfido ligands / cyclo-Selenido ligands / Iridacycles ~~ ~~ Cp\*Ir(PMe3)C12 (1) reacts with chalcogenide ligand sources such as (NH4)& (x x lo), (NEt&Se6, and H,Se to yield the half-sandwich complexes Cp\*Ir(PMe,)(S,) In = 4 (2a), 6 (4a)l and Cp