Synthesis, reactions, and crystal structure of 5-azido-6-O-benzoyl-3,5-dideoxy-3-fluoro-1,2-O-isopropylidene-α-d-glucofuranose
✍ Scribed by C.-Kuan Lee; Huixin Jiang; Lip Lin Koh
- Book ID
- 107726133
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 793 KB
- Volume
- 225
- Category
- Article
- ISSN
- 0008-6215
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📜 SIMILAR VOLUMES
Several mono-and bi-cyclic polyhydroxylated alkaloids, isolated from plants', are specific and potent glycosidase inhibitors3, including those involved in the processing of glycoproteins4. Convenient intermediates for the synthesis of these compounds are 5-azido-5-deoxy sugar derivatives. Attempts
3-0-(6-0-Acetyl-2,3-anhydro-4-deoxy-a-L-ribo-hexopyranosyl)-l,2:5,6-di-O-isopropylidene-a-D-glucofuranose has been synthesised and its monocrystal investigated by X-ray diffraction methods. The compound crystallises in the orthorhombic system, space group P2,2,2t, with cell constants a = 8.790( 7),