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Synthesis, photooxygenation, and Diels-Alder reactions of 1-methyl-4a,5,6,7,8,8a-trans-hexahydronaphthalene and 1,4a-dimethyl-4a,5,6,7,8,8a-trans-hexahydronaphthalene

โœ Scribed by Sasson, Isaac; Labovitz, Jeffrey

Book ID
126167254
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
881 KB
Volume
40
Category
Article
ISSN
0022-3263

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Selective rearrangements of 4a,5-epoxide
Selective rearrangements of 4a,5-epoxides of 4,4-dimethyl-1,2,3,4,6,8a-hexahydronaphthalenes.
โœ Steven P. Tanis; Yousef M. Abdallah; Paul G. Williard ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 303 KB

g oxidation selectivity of a number of 4 r-dimethyl-1,2,3,4,6,8a-hexahydronapht alenes 4 were examined. Exposure of the isolated a-epoxides 7 provided excellent yields (79-92x) of rearranged fused indene-oxetanes 8. Treatment of dF\_epoxides 5 with BF3\* OEtz also yields oxetanes 6 and related alcoh