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Synthesis, Optical Resolution and Complexation Properties of Inherently Chiral Monoalkylated p-tert -Butyl-(1,2)-calix[4]crown Ethers

โœ Scribed by Arnaud-Neu, Francoise; Caccamese, Salvatore; Fuangswasdi, Saowarux; Pappalardo, Sebastiano; Parisi, Melchiorre F.; Petringa, Ada; Principato, Grazia


Book ID
127297119
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
278 KB
Volume
62
Category
Article
ISSN
0022-3263

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The hetero-armedp-(tert -butyl)calix[4]arene 1 was synthesized by a stepwise procedure. This ligand presented a very strong complexing behavior towards Cu', giving the chiral complex 2 and parent species when reacted with Cu" salts. High-resolution NMR techniques were employed for the characterizati