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Synthesis ofN-[1-(1H-Benzimidazol-2-ylsulfanyl)-2,2,2-trichloroethyl]arenesulfonamides by Reaction ofN-(2,2,2-Trichloroethylidene)arenesulfonamides with 1H-benzimidazole-2-thiol

✍ Scribed by I. B. Rozentsveig, V. Yu. Serykh, G. G. Levkovskaya


Book ID
114993919
Publisher
SP MAIK Nauka/Interperiodica
Year
2012
Tongue
English
Weight
158 KB
Volume
48
Category
Article
ISSN
1070-4280

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In the molecule of the title compound, C 10 H 10 N 2 O 2 S, the benzimidazole ring system and the plane through the non-H atoms of the methyl mercaptoacetate group form a dihedral angle of 81.75 (1) . The crystal structure is stabilized by N-HÁ Á ÁN hydrogen bonds, giving infinite chains along the [

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Molecules of the title compound, C~10~H~12~N~2~OS, are interconnected by Nβ€”H...O hydrogen bonds of moderate strength into infinite chains. There are also intramolecular Oβ€”H...N bonds of moderate length. Weaker interactions are represented by Cβ€”H...N bonds as well as by π–π interactions between the i