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Synthesis of π-conjugated polymers possessing 1,3-butadiene-1,4-diyl units by reactions of regioregular organometallic polymer having titanacyclopentadiene moieties in the main chain

✍ Scribed by Kiyohiko Atami; Tomoko Kino; Wei-Min Zhou; Hiroki Nishiyama; Ikuyoshi Tomita


Book ID
116898604
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
252 KB
Volume
159
Category
Article
ISSN
0379-6779

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## Abstract A π‐conjugated polymer having 1,4‐bismercapto‐substituted 1,3‐diene units in the main chain was prepared by the novel polymer reaction of a regioregular organometallic polymer having titanacyclopentadiene‐2,5‐diyls units with benzenesulfenyl chloride. The number‐average molecular weight

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## Abstract **Summary:** Three new soluble __π__‐conjugated polymers containing 1,3,5‐triazine units in the main chain, Pa–Pc, were synthesized. The polymers showed optical properties in solution that were mainly dependant on the properties of the substituting R groups, on the triazine ring. Hence,