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Synthesis of Δ 8,9 - and Δ 9,10 -Octal-1-one 1

✍ Scribed by HOUSE, HERBERT O.; THOMPSON, HUGH W.


Book ID
126253524
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
836 KB
Volume
26
Category
Article
ISSN
0022-3263

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Easy conjugate additions to Δ1(9)-octal-
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## Conjugate additions of Zithiated arylacetonitriles to 2-octaZones give good yields of cis-decalone products. Z'he stereochemistry of the adducts is determined by 13 C NMR spectroscopy. Conjugate additions of enolates2, 3 4 cuprates , allylsilanes and aluminum or zirconium acetylides (via nick

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## Abstract Die UV‐Absorption der Jodkomplexe von Cycloolefinen wird gemessen und nach der von LONG und NEUZIL für Olefine entwickelten Methode zur Analyse von Δ^1.9^‐ und Δ^9.10^‐Octalingemischen verwendet.