## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Synthesis of γ-hydroxy ketones by LiClO4-catalyzed addition of lithium enolates to 1,2-Epoxides
✍ Scribed by Marco Chini; Paolo Crotti; Lucilla Favero; Mauro Pineschi
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- French
- Weight
- 270 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4039
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## Abstract Addition reactions of diethylamine onto 1,4‐divinylbenzene (DVB) catalyzed by lithium diethylamide were examined to find a synthetic route to a group of new monomers possessing dialkylamino substituents, which is expected to be a starting material for biomedical polymers such as ionic p
But-1-en-3-ynes react with lithium and chlorotrimethylsilane in THF to give 1,4-bis(trimethylsilyl)buta-2,3dienes. Epoxidation of these allenes leads to oxyallyl species which are trapped by nucleophilic reagents to give 1,4-bis(trimethylsilyl)butan-3-ol-2-one derivatives.