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SYNTHESIS OF γ-CARBOXYGLUTAMIC ACID AND ITS DERIVATIVES VIA MANNICH-BASE CONDENSATION

✍ Scribed by JUHÁSZ, ATTILA ;BAJUSZ, SÁNDOR

Book ID
115097586
Publisher
Wiley (Blackwell Publishing)
Year
2009
Tongue
English
Weight
342 KB
Volume
15
Category
Article
ISSN
0367-8377

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Protected S-pyroglutamic acid can be deprotonated specifically at the y-position. The resulting enolate can be converted into y-carboxyglutamic acid in optically pure form. The naturally occurring aminoacid r\_carboxyglutamtc acid (1; Gla) is a constituent of prothrombin and other proteins.1 The nat