Reactions of Zamino-2-deoxy-D-glucose and its N-butyl derivative with lethoxy-Znitroethene produced 2-deoxy-2-[(2-nitrovinyl)amino]-D-glucose ( 6) and its N-butyl derivative (8), respectively, in high yields. The spectra of these compounds indicated that they were cu,p-anomeric mixtures, and also th
✦ LIBER ✦
Synthesis of β-nitropyrroles from amino sugars and nitroacetone
✍ Scribed by Jose-Luis Chiara; Antonio Gómez-Sánchez; Francisco-Javier Hidalgo; Inmaculada Yruela
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 527 KB
- Volume
- 188
- Category
- Article
- ISSN
- 0008-6215
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## Abstract Starting from the enantiomerically pure building block 2 which is readily available from D‐asparagine α,β‐disubstituted β‐amino nitriles and β‐amino acids could be synthesized. After deprotonation of the nitrile α‐position the introduction of substituents was performed by alkylation of