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Synthesis of β-lactams by condensation of the tin enolates of 2-pyridylthioesters with imines. A comparison between titanium and tin enolates

✍ Scribed by Rita Annunziata; Maurizio Benaglia; Mauro Cinquini; Franco Cozzi; Laura Raimondi


Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
490 KB
Volume
50
Category
Article
ISSN
0040-4020

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Enol acetates derived from saturated ketones are converted to a,&unsaturated ketones by heating with ally1 methyl carbonate in MeCN by bimetallic catalysis of palladiumphosphine complex and tin methoxide. Conversion of saturated ketones to corresponding a,&unsaturated ketones is an important synthet