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Synthesis of β-di and tribromoporphyrins and the crystal structures of antipodal tri-substituted Zn(II)-porphyrins

✍ Scribed by P. Bhyrappa; V. Velkannan

Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
414 KB
Volume
51
Category
Article
ISSN
0040-4039

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✦ Synopsis

Bromination of meso-tetraphenylporphyrin, H 2 TPP with controlled amounts of N-bromosuccinimide at ambient conditions in CHCl 3 produced b-dibromo and tribromotetraphenylporphyrins. The regiochemistry of the ZnTPPR 3 (R = Br, Ph) complexes indicate the antipodal substitution at the b-pyrrole positions.

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