Synthesis of β configured 2′,3′-unsaturated pentopyranosyl nucleosides
✍ Scribed by Bodgan Doboszewski; Norbert Blaton; Piet Herdewijn
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 155 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The α,β‐unsaturated D‐sugar aldehyde 2, prepared from tri‐__O__‐acetyl‐D‐glucal, was converted into 1‐__O__‐acetyl‐3‐azido‐2,3‐dideoxy‐α‐D‐__arabino__‐pyranose (3) by reaction with sodium azide in a mixture of acetic acid and water followed by acetylation. Reaction of 3 with silylated p
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