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Synthesis of α,ω-Difunctionalized Oligo- and Poly( p - phenyleneethynylene)s

✍ Scribed by Francke, V.; Mangel, T.; Müllen, K.

Book ID
126087978
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
163 KB
Volume
31
Category
Article
ISSN
0024-9297

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Palladium-catalyzed synthesis of poly(p-
Palladium-catalyzed synthesis of poly(p-phenyleneethynylene)s
✍ Victor A. Solomin; Walter Heitz 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 568 KB

## Abstract Poly(__p__‐phenyleneethynylene)s were obtained by reacting 1,4‐dihaloarenes with 2‐methyl‐3‐butyn‐2‐ol in a two‐step one‐pot process. In the first step a dihaloarene is reacted with two equivalents of 2‐methyl‐3‐butyn‐2‐ol at room temperature in the presence of an aqueous base. For poly