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Synthesis of α,β-unsaturated aldehydes via 1-aminopropa-1,2-dienes: mechanistic studies

✍ Scribed by J. Cymerman Craig; Nnochiri N. Ekwuribe

Publisher: Elsevier Science
Year: 1980
Tongue: French
Weight: 172 KB
Volume: 21
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)92812-0

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✦ Synopsis

A facile prototropic rearrangement of N-(prop-Z-ynyljamines to l-aminopropa-1,2-dienes, followed by acid hydrolysis, affords a novel synthesis of a,@-unsaturated aldehydes.

The mechanism of the reaction has been examined by deuterium labeling.

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