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Synthesis of α-tocopherol analogs with unsaturated side chain and their transformation into the corresponding chromans with ω-functionalized side chain

✍ Scribed by V. N. Odinokov; A. Yu. Spivak; G. A. Emelianova; B. I. Kutepov; L. M. Khalilov

Book ID: 110333533
Publisher: Springer
Year: 2001
Tongue: English
Weight: 211 KB
Volume: 50
Category: Article
ISSN: 1573-9171
DOI: 10.1023/a:1015086326009

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## Abstract (+)‐5′‐Oxa‐gloeosporone (2), an analog of the natural germination self‐inhibitor (−)‐gloeosporone (1), is synthesized, largely following our previously published route to the parent compound. Thus, the hydroxybutyl side chain of 2 was introduced by hydroboration of a butenyl group (→ 14