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Synthesis of α-substituted ketones by reaction of metallated ketimines with allyl compounds under the action of palladium complexes

✍ Scribed by U. M. Dzhemilev; D. L. Minsker; L. M. Khalilov; A. G. Ibragimov


Book ID
112447138
Publisher
Springer
Year
1988
Tongue
English
Weight
412 KB
Volume
37
Category
Article
ISSN
1573-9171

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✍ Jiro Tsuji; Ichiro Minami; Isao Shimizu 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 115 KB

Enol acetates derived from saturated ketones are converted to a,&unsaturated ketones by heating with ally1 methyl carbonate in MeCN by bimetallic catalysis of palladiumphosphine complex and tin methoxide. Conversion of saturated ketones to corresponding a,&unsaturated ketones is an important synthet