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Synthesis of α- and/or γ-Benzoyloxy-α,β-enones from α-Halo-α,β-enones.

✍ Scribed by Yujiro Hayashi; Mitsuru Shoji; Satoshi Kishida


Publisher
John Wiley and Sons
Year
2005
Weight
31 KB
Volume
36
Category
Article
ISSN
0931-7597

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Iterative Cyclopentane Annulation of α,β
✍ Dipl.-Chem. Maria Dorsch; Prof. Dr. Volker Jäger; Dipl.-Chem. Wolfgang Spönlein 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 234 KB

tation in 3 (AAG' > 6 kcal/mol). 8n-"Antiaromaticity" in the cycloheptatrienide ion, on the other hand, cannot be of much significance energetically, since the difference in barriers for 1 and 2 is only 3.5 kcal/mol. According to the Xray structure analysis, 1 . 2 T H F has a "pentadienide ion" stru