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Synthesis of α- and ω-norbornenyl-polybutadiene macromonomers and their ring-opening metathesis polymerization

✍ Scribed by Valérie Héroguez; Jean-Luc Six; Yves Gnanou; Michel Fontanille

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
626 KB
Volume
199
Category
Article
ISSN
1022-1352

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✦ Synopsis

Norbornene-ended polybutadiene (PBu) macromonomers have been prepared via two different routes: a-norbornenyl-polybutadiene was derived from a norbornene-containing carbanionic initiator, whereas w-norbornenyl samples were obtained through deactivation of living polybutadienyl anions by a norbornene-based deactivator. Out of four alkylidene complexes tried, the molybdenum alkylidene complex that contains two alkoxide ligands was found to be the most suitable initiator for the ring-opening metathesis polymerization of these macromonomers.

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