Synthesis of zincic phthalocyanine derivative functionalized with four peripheral tetrathiafulvalene units

✍ Scribed by Yingyu Hu; Yongjia Shen

• Book ID: 102339907
• Publisher: Journal of Heterocyclic Chemistry
• Year: 2002
• Tongue: English
• Weight: 44 KB
• Volume: 39
• Category: Article
• ISSN: 0022-152X
• DOI: 10.1002/jhet.5570390535

✦ Synopsis

Abstract

A zincic phthalocyanine (Pc) derivative functionalized with four peripheral substituted tetrathiafulvalene (TTF) units has been synthesized. The intermediates and target compound have been characterized by ^1^H‐nmr, ^13^C‐nmr, ms, EA, uv‐vis and mp. The molecular weight of H~2~Pc‐TTF~4~ can not be found in mass spectra. ^1^H‐nmr spectra and mp determination show both H~2~PC‐TTF~4~ and ZnPc‐TTF~4~ are isomer‐mixtures. Uv‐vis spectra indicate that the aggregation of H~2~PC‐TTF~4~ is solvent dependent and the introduction of Zn atom affects the solubility of the assembly.