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Synthesis of (Z)-tetradec-11-en-1-ol and (Z)-hexadec-11-en-1-ol from dodecane-1,12-diol

โœ Scribed by L. I. Zakharkin; V. V. Guseva


Book ID
104817834
Publisher
Springer
Year
1984
Tongue
English
Weight
263 KB
Volume
20
Category
Article
ISSN
0009-3130

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CrCl 2 converts trichloromethylcarbinols under mild conditions to (E)-a-haloalkylidene chromium carbenoids which add to aldehydes or are quenched with water affording 2-haloalk-2(Z)-en-1-ols and 1-chloro-1(Z)-alkenes, respectively, in high yield.