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Synthesis of Water-Soluble Polymethacrylates by Living Anionic Polymerization of Trialkylsilyl-Protected Oligo(ethylene glycol) Methacrylates

✍ Scribed by Ishizone, Takashi; Han, Seok; Okuyama, Syunsuke; Nakahama, Seiichi

Book ID
121480075
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
115 KB
Volume
36
Category
Article
ISSN
0024-9297

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## Abstract Anionic polymerizations of 2‐[(trimethylsilyl)oxy]ethyl methacrylate (1), 2‐[(__tert__‐butyldimethylsilyl)oxy]ethyl methacrylate (2), and 2‐[(methoxymethyl)oxy]ethyl methacrylate (3), the protected forms of 2‐hydroxyethyl methacrylate (HEMA), were carried out in THF at βˆ’78Β°C with 1,1‐di