Synthesis of vinyldiphenylphosphines by Pd-catalyzed cross-coupling reactions of diphenylphosphine with alkenylhalides

✍ Scribed by Marina A. Kazankova; Evgeniy A. Chirkov; Andrew N. Kochetkov; Irina V. Efimova; Irina P. Beletskaya

• Publisher: Elsevier Science
• Year: 1999
• Tongue: French
• Weight: 167 KB
• Volume: 40
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(98)02359-4

✦ Synopsis

o~-and [3-alkoxy (or-and [3-dialkylamino)

vinylphosphines were synthesized by palladium catalyzed reactions of the corresponding vinylhalides with diphenylphosphine or diphenyltrimethylsilylphosphinein high yields.