## Abstract Hydroxy‐terminated telechelic poly(2‐chloroethyl vinyl ether) (poly(CEVE)) was synthesized by water‐based end‐capping reaction of living poly(CEVE) with the initiating system CH~3~CHClOCH~2~CH~2~OCOCH~3~/ZnCl~2~ in CH~2~Cl~2~ at −40°C and subsequent end‐group transformation of the ace
Synthesis of vinyl ether-capped telechelic poly(tetrahydrofuran)
✍ Scribed by Tamotsu Hashimoto; Tomohiro Furukawa; Toshiyuki Kodaira
- Book ID
- 102492080
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 176 KB
- Volume
- 17
- Category
- Article
- ISSN
- 1022-1336
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Vinyl ether‐terminated telechelic poly(tetrahydrofuran) (poly(THF)) was synthesized by the reaction of a bifunctional living cationic polymer of THF with an excess of Na⊕⊖OCH~2~CH~2~OCHCH~2~ in THF at 0°C. The obtained polymer has narrow molecular weight distribution and end functionality close to two.
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## Abstract This study concerns the synthesis of C~60~‐capped vinyl ether (VE) oligomers with well‐defined structure by living cationic polymerization technique. The VE oligomers bearing C~60~ at the chain end were prepared by addition reaction between monoocynylfulleride anions and living cationic
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